Selective Spectrophotometric Determination of Aluminium with Xylenol Orange in Acidic Media Using Partial Least Square Method

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Simultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares

A partial least squares (PLS) calibration model was developed for the simultaneous spectrophotometricdetermination of Pb (ΙΙ), Cu (ΙΙ) and Ni (ΙΙ) using xylenol orange as a chromogenic reagent. The parameterscontrolling behavior of the system were investigated and optimum conditions were selected. The calibrationgraphs were linear in the ranges of 0.0–9.091, 0.0–2.719 and 0.0–2.381 ppm for lead...

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simultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares

a partial least squares (pls) calibration model was developed for the simultaneous spectrophotometricdetermination of pb (ιι), cu (ιι) and ni (ιι) using xylenol orange as a chromogenic reagent. the parameterscontrolling behavior of the system were investigated and optimum conditions were selected. the calibrationgraphs were linear in the ranges of 0.0–9.091, 0.0–2.719 and 0.0–2.381 ppm for lead...

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multiwavelength pectrophotometric determination of stability constants of 4-(2– thiazolylazo) resorcinol (tar) with la3+, y3+ and th4+ in organic-water mixed solvents by chemometrics method & simultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares calibration method

تشکیل کمپلکس های tarبا یون های لانتانیم, ایتریم و توریم در دمای 25 درجه، قدرت یونی ثابت 0.1 مولار و در ph ثابت در مخلوط حلال های اتانول – آب و استونیتریل – آب با استفاده از روش های اسپکتروفوتومتری مورد بحث و بررسی قرار گرفت. داده های اسپکتروفوتومتری با استفاده از نرم افزار squad پردازش شدند تا ثابت های تشکیل کمپلکس اندیکاتور – فلز را محاسبه کند. نتایج نشان می دهد که درصد حلال آلی در مخلوط حلال ...

15 صفحه اول

Solid Phase Spectrophotometric Determination Of Cobalt By Xylenol Orange

A simple and sensitive solid phase spectrophotometric method for the determination of cobalt is proposed based on the reaction between cobalt and xylenol orange (XO). The reaction product is fixed on the anionic exchanger resin sephadex QAE A-25 at pH= 5. The optical absorbance of the anionic gel like resin, packed in a 1.00 mm cell is directly measured at 588.0 nm. The linear range of calibrat...

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Partial Least Square and Parallel Factor Analysis Methods Applied for Spectrophotometric Determination of Cefixime in Pharmaceutical Formulations and Biological Fluid

In this study, the direct determination of cefixime as an anti-bacterial agent, in pharmaceutical formulations, urine and human blood plasma was conducted based on spectrophotometric measurements using parallel factor analysis (PARAFAC) and partial least squares (PLS). The calibration set was composed of fourteen solutions in the range of 0.50- 9.00 µg mL-1. PLS models were calculated at each p...

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ژورنال

عنوان ژورنال: Asian Journal of Chemistry

سال: 2013

ISSN: 0970-7077,0975-427X

DOI: 10.14233/ajchem.2013.13432